Derive an expression for the work obtained in an isothermal reversible expansion of an ideal gas.
Answer
590.5k+ views
Hint Isothermal process is a thermodynamic process in which the temperature of the system will remain constant throughout the process. A reversible reaction is the kind of reaction that can return to its initial state by making some changes. Here we have an isothermal reversible expansion of an ideal gas.
Formula used
$PV = nRT$ Where, $P$ stands for the pressure of the system, $V$ stands for the volume of the system, $n$ stands for the number of moles of gas in the system, $R$ stands for the universal gas constant and $T$ stands for the temperature of the system.
Complete Step by step solution
Here we consider $n$ moles of ideal gas contained in a container fitted with a weightless and frictionless piston. Here the work done is in expanding the volume. Let $dV$ be the small change in volume against the external pressure.
Now the work done in increasing the volume by a small element $dV$ can be written as,
$dW = - PdV$
The total work done for the expansion of the gas from its initial volume ${V_1}$ to the final volume ${V_2}$ can be obtained by integrating the small work done
$W = - \int\limits_{{V_1}}^{{V_2}} {PdV} $
In the case of an ideal gas, we can write the ideal gas equation as,
$PV = nRT$
$ \Rightarrow P = \dfrac{{nRT}}{V}$
$W = - \int\limits_{{V_1}}^{{V_2}} {\dfrac{{nRT}}{V}} dV$
For isothermal expansion the temperature $T$is constant, hence we can write
$W = - nRT\int\limits_{{V_1}}^{{V_2}} {\dfrac{{dV}}{V}} $
$W = - nRT\left[ {\ln V} \right]_{{V_1}}^{{V_2}}$
Applying the limits we get,
$W = - nRT\left( {\ln {V_2} - \ln {V_1}} \right)$
$W = - nRT\ln \left( {\dfrac{{{V_2}}}{{{V_1}}}} \right)$
Converting into logarithm we get,
$W = - 2.303nRT\log \left( {\dfrac{{{V_2}}}{{{V_1}}}} \right)$………………………………………………………………………..equation
This is the total work done for the isothermal reversible expansion of an ideal gas.
Note
The work done can be expressed in terms of pressure also.
At constant temperature
${P_1}{V_1} = {P_2}{V_2}$
From this we get
$\dfrac{{{V_2}}}{{{V_1}}} = \dfrac{{{P_1}}}{{{P_2}}}$
Substituting in the above expression in equation
We get,
$W = - 2.303nRT\log \left( {\dfrac{{{P_1}}}{{{P_2}}}} \right)$……………………………………………………………………equation
Equation and gives the expression for the work done by an isothermal reversible expansion of an ideal gas.
Formula used
$PV = nRT$ Where, $P$ stands for the pressure of the system, $V$ stands for the volume of the system, $n$ stands for the number of moles of gas in the system, $R$ stands for the universal gas constant and $T$ stands for the temperature of the system.
Complete Step by step solution
Here we consider $n$ moles of ideal gas contained in a container fitted with a weightless and frictionless piston. Here the work done is in expanding the volume. Let $dV$ be the small change in volume against the external pressure.
Now the work done in increasing the volume by a small element $dV$ can be written as,
$dW = - PdV$
The total work done for the expansion of the gas from its initial volume ${V_1}$ to the final volume ${V_2}$ can be obtained by integrating the small work done
$W = - \int\limits_{{V_1}}^{{V_2}} {PdV} $
In the case of an ideal gas, we can write the ideal gas equation as,
$PV = nRT$
$ \Rightarrow P = \dfrac{{nRT}}{V}$
$W = - \int\limits_{{V_1}}^{{V_2}} {\dfrac{{nRT}}{V}} dV$
For isothermal expansion the temperature $T$is constant, hence we can write
$W = - nRT\int\limits_{{V_1}}^{{V_2}} {\dfrac{{dV}}{V}} $
$W = - nRT\left[ {\ln V} \right]_{{V_1}}^{{V_2}}$
Applying the limits we get,
$W = - nRT\left( {\ln {V_2} - \ln {V_1}} \right)$
$W = - nRT\ln \left( {\dfrac{{{V_2}}}{{{V_1}}}} \right)$
Converting into logarithm we get,
$W = - 2.303nRT\log \left( {\dfrac{{{V_2}}}{{{V_1}}}} \right)$………………………………………………………………………..equation
This is the total work done for the isothermal reversible expansion of an ideal gas.
Note
The work done can be expressed in terms of pressure also.
At constant temperature
${P_1}{V_1} = {P_2}{V_2}$
From this we get
$\dfrac{{{V_2}}}{{{V_1}}} = \dfrac{{{P_1}}}{{{P_2}}}$
Substituting in the above expression in equation
We get,
$W = - 2.303nRT\log \left( {\dfrac{{{P_1}}}{{{P_2}}}} \right)$……………………………………………………………………equation
Equation and gives the expression for the work done by an isothermal reversible expansion of an ideal gas.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
Find the value of the expression given below sin 30circ class 11 maths CBSE

One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

Bond order ofO2 O2+ O2 and O22 is in order A O2 langle class 11 chemistry CBSE

